Reduction of CO2 to methanol using aluminum ester FLPs
نویسندگان
چکیده
منابع مشابه
CO2 reduction via aluminum complexes of ammonia boranes.
Reactions of amine-boranes NH3BH3, Me2NHBH3, or Me3NBH3 with AlX3 (X = Cl, Br, I, C6F5) have been examined. The species AlBr3·H3BNMe3 2, Al(C6F5)3·H3BNMe3 3, Al(C6F5)3·H3BNHMe2 4 and Al(C6F5)3·H3BNH3 5 have been prepared and isolated. The analogous reaction of B(C6F5)3 and H3BNMe3 results in C6F5-transfer and the formation of (C6F5)BH2·NMe3 6. While the adduct 6 was unreactive to CO2, species 3...
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ژورنال
عنوان ژورنال: Inorganic Chemistry Communications
سال: 2015
ISSN: 1387-7003
DOI: 10.1016/j.inoche.2015.10.009